Carbon capture strategy could lead to CO2 emission-free cars

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[a short-term solution, unless one had carbon capture on vehicles consuming high efficiency bio-fuels - such algae sourced materials - allowing one to turn the CO2 clock backwards]

Researchers at the Georgia Institute of Technology have developed a strategy to capture, store and eventually recycle carbon from vehicles to prevent the pollutant from finding its way from a car tailpipe into the atmosphere. Georgia Tech researchers envision a zero emission car, and a transportation system completely free of fossil fuels.

Technologies to capture carbon dioxide emissions from large-scale sources such as power plants have recently gained some impressive scientific ground, but nearly two-thirds of global carbon emissions are created by much smaller polluters — automobiles, transportation vehicles and distributed industrial power generation applications (e.g., diesel power generators).

The Georgia Tech team’s goal is to create a sustainable transportation system that uses a liquid fuel and traps the carbon emission in the vehicle for later processing at a fueling station. The carbon would then be shuttled back to a processing plant where it could be transformed into liquid fuel. Currently, Georgia Tech researchers are developing a fuel processing device to separate the carbon and store it in the vehicle in liquid form.

The research was published in Energy Conversion and Management. The research was funded by NASA, the U.S. Department of Defense NDSEG fellowship program and Georgia Tech’s CEO (Creating Energy Options) Program.

“Presently, we have an unsustainable carbon-based economy with several severe limitations, including a limited supply of fossil fuels, high cost and carbon dioxide pollution,” said Andrei Fedorov, associate professor in the Woodruff School of Mechanical Engineering at Georgia Tech and a lead researcher on the project. “We wanted to create a practical and sustainable energy strategy for automobiles that could solve each of those limitations, eventually using renewable energy sources and in an environmentally conscious way.”

Little research has been done to explore carbon capture from vehicles, but the Georgia Tech team outlines an economically feasible strategy for processing fossil or synthetic, carbon-containing liquid fuels that allows for the capture and recycling of carbon at the point of emission. In the long term, this strategy would enable the development of a sustainable transportation system with no carbon emission.

Georgia Tech’s near-future strategy involves capturing carbon emissions from conventional (fossil) liquid hydrocarbon-fueled vehicles with an onboard fuel processor designed to separate the hydrogen in the fuel from the carbon. Hydrogen is then used to power the vehicle, while the carbon is stored on board the vehicle in a liquid form until it is disposed at a refueling station. It is then transported to a centralized site to be sequestered in a permanent location currently under investigation by scientists, such as geological formations, under the oceans or in solid carbonate form.


In the long-term strategy, the carbon dioxide will be recycled forming a closed-loop system, involving synthesis of high energy density liquid fuel suitable for the transportation sector.

Georgia Tech settled on a hydrogen-fueled vehicle for its carbon capture plan because pure hydrogen produces no carbon emissions when it is used as a fuel to power the vehicle. The fuel processor produces the hydrogen on-board the vehicle from the hydrocarbon fuel without introducing air into the process, resulting in an enriched carbon byproduct that can be captured with minimal energetic penalty. Traditional combustion systems, including current gasoline-powered automobiles, have a combustion process that combines fuel and air — leaving the carbon dioxide emissions highly diluted and very difficult to capture.

“We had to look for a system that never dilutes fuel with air because once the CO2 is diluted, it is not practical to capture it on vehicles or other small systems,” said David Damm, PhD candidate in the School of Mechanical Engineering, the lead author on the paper and Fedorov’s collaborator on the project.

The Georgia Tech team compared the proposed system with other systems that are currently being considered, focusing on the logistic and economic challenges of adopting them on a global scale. In particular, electric vehicles could be part of a long-term solution to carbon emissions, but the team raised concerns about the limits of battery technology, including capacity and charging time.

The hydrogen economy presents yet another possible solution to carbon emissions but also yet another roadblock — infrastructure. While liquid-based hydrogen carriers could be conveniently transported and stored using existing fuel infrastructure, the distribution of gaseous hydrogen would require the creation of a new and costly infrastructure of pipelines, tanks and filling stations.

The Georgia Tech team has already created a fuel processor, called CO2/H2 Active Membrane Piston (CHAMP) reactor, capable of efficiently producing hydrogen and separating and liquefying CO2 from a liquid hydrocarbon or synthetic fuel used by an internal combustion engine or fuel cell. After the carbon dioxide is separated from the hydrogen, it can then be stored in liquefied state on-board the vehicle. The liquid state provides a much more stable and dense form of carbon, which is easy to store and transport.

The Georgia Tech paper also details the subsequent long-term strategy to create a truly sustainable system, including moving past carbon sequestration and into a method to recycle the captured carbon back into fuel. Once captured on-board the vehicle, the liquid carbon dioxide is deposited back at the fueling station and piped back to a facility where it is converted into a synthetic liquid fuel to complete the cycle.

Now that the Georgia Tech team has come up with a proposed system and device to produce hydrogen and, at the same time, capture carbon emissions, the greatest remaining challenge to a truly carbon-free transportation system will be developing a method for making a synthetic liquid fuel from just CO2 and water using renewable energy sources, Fedorov said. The team is exploring a few ideas in this area, he added.

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Source: Georgia Institute of Technology

http://www.physorg.com/news121960026.html

Capt'n Midnight

there is a picture on wikipedia about wind to wheel efficiency
if you use batteries you get about 86% efficiency , if you use hydrogen fuel cells you are down to about 40%


years ago I saw an article about submarines that used stirling engine. the hull was made from doughnuts filled with compressed oxygen and the waste carbon dioxide went there after wards, the pressure made the hull stronger. wonder how much air you could store for a car that runs on compressed air/ uses it to increase engine effficiency because less power wasted on compression stroke. Since the car is the tank you save weight on the body and crash protection improves too.

dhaslam

Looks like battery cars are just around the corner. The three main battery problems seem to sorted out, charging speed, capacity and useable life, although these properties may not all be available in the same battery yet. The problem is really back to sources of electricity. Solar power from the Sahara and offshore wind seem to be the most promising at present. For both sources batteries are needed.

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Capt'n Midnight wrote: »

there is a picture on wikipedia about wind to wheel efficiency
if you use batteries you get about 86% efficiency , if you use hydrogen fuel cells you are down to about 40%

1) Hydrogen kit efficiency is improving all of the time
2) Battery efficiency is improving all of the time

They require similar infrastructure in many respects.

H2 is just another battery technology.

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